First of all, learn what all of the symbols in each equation mean. For instance, in v^2 = u^2 + 2ax, v is the final velocity, u is the initial velocity, a is the acceleration and x is the displacement. This equation is only valid for constant acceleration, so a is constant. Also, x is the difference in position of the particle from when the velocity is u to when to the velocity is v. Don't just rote learn and formula bash.
So for your equation, for instance, the policeman will catch up with the car when it travels the same distance as the car.
The question you gave is slightly complicated. Let us break it down.
After a time t hours, the car will travel 80 km/h * t hours = 80t km.
The policeman's movement falls into three stages. When accelerating to 80 km/h in 10s or 1/360 hours, we're given an initial speed (0), final speed (80 km/h) and time (10 s). To find the displacement, we use x=t(u+v)/2 = 1/360 hours*(0+80)/2 km/hr = 1/9 km.
Then, in the second stage, the policeman goes from 80 to 100 km/h in 5 s. Using the above formula again, we have x = t/2*(u+v) = 1/2*5/3600 hours*(80+100)/2 km/hr = 450/7200 km = 45/720 km = 9/144 km = 1/16 km. (as you can see I'm doing this as I go LOL)
Note how I've written in all of the units. You can cancel them like they were regular pronumerals and this shows you the importance of converting units; if I had 1 km/h * 1 second = 1 km s/h, I would have to use the fact that 1 second is 1/3600 of an hour to get 1/3600 km.
In the third stage, the policeman travels for a time t hours - 15 seconds = (t-15/3600) hours = (t-1/240) hours. As it moves at a constant 100 km/hr speed, the distance travelled in this third stage is speed*time = (t-1/240)*100 km. In total, for a time t, the policeman travels 1/16 + 1/9 + 100(t-1/240) km. This is equal to the distance travelled by the car, so set this equal to 80t. Solve for t and you'll have the time in hours.
I get 20t = 100/240 - 25/144 = 50/120 - 25/144 = 60/144 - 25/144 = 35/144
t = 7/576 hours. Someone please check my working. In an exam, please use your calculator